The expansion of Carbon Capture, Utilization, and Storage (CCUS) highlights the growing need for carbon dioxide (CO2) pipeline transportation. While pure CO2 is non-corrosive, impurities such as H2O and NO2 create a corrosive environment that risks pipeline integrity. This study investigates how H2O and NO2 concentrations, along with temperature, influence corrosion under CO2 pipeline conditions. The investigation was performed in an autoclave setup emulating a linear velocity of 0.96 m/s at 100 bar and temperatures of 5 °C and 25 °C, testing X52 and GR70, and a more corrosion-resistant 9Cr alloy. The results indicated that the presence of NO2 elevated the corrosion rate compared to scenarios without. Low H2O concentration led to a corrosion rate of up to five times higher at 5 °C, compared to at 25 °C, in the presence of NO2. Low to moderate corrosion was observed for the carbon steels without NO2 and with 70 ppmv H2O at both temperatures. Reducing the H2O concentration below 70 ppmv and removing NO2, while SO2 and O2 are present, will only result in low to moderate corrosion in the carbon steel CO2 pipeline. The corrosion rate for X52 and GR70 was 0.065 mm/y and 0.016 mm/y higher or 5 and 3 times greater, respectively, at 5 °C compared to 25 °C. The study concludes that H2O should be maintained below 70 ppmv and NO2 should be eliminated to prevent severe corrosion. Emphasizing the importance of CO2 specification compliance and the need for further research into CO2 compositions that align with the specifications.
This study investigates the complex and still insufficiently understood interactions between ocean currents and offshore wind farms (OWFs), with a focus on local-scale hydrodynamic effects near individual wind turbine foundations. Despite growing interest in the environmental impacts of OWFs, empirical field data on local-scale current dynamics within wind farms remain sparse. This technical report describes the results from a field campaign, which was conducted within the Anholt OWF in the Kattegat over a 9-day period in August 2024.
As more offshore wind energy projects are implemented, the risk of interactions between farms becomes more pronounced. While reduced surface roughness over water enhances airflow stability, it can also extend wake effects on downstream turbines. The study aims to enhance the understanding of wake interactions and efficiency variations based on the distance between neighboring farms. To assess the impact of neighboring farms across different scenarios and features, a methodology is developed to achieve computational optimality using an open-source Python-based library, PyWake, then verified by a well-established CFD software, Meteodyn. Then, the methodology is applied to a Brazilian offshore wind project currently under licensing as a reference point. The results indicate a 1–3% reduction in Annual Energy Production following the current Brazilian regulation for onshore projects of 20 times the blade tip height, as the minimum distance. This reduction translates to an approximate 3% increase in the Levelized Cost of Energy and a nearly 24% decrease in Net Present Value. These findings are crucial for offshore wind energy planning and its sustainable growth, indicating the need to define a minimum distance for the regulatory bodies. This would not only avoid future disputes but also enhance investor confidence.
Determination of the causes of mortality in stranded marine mammals can contribute valuable information for conservation of wild populations, as well as contribute to risk assessments for different pathogens, hosts, and environmental conditions. This study examined necropsy reports for harbor (Phoca vitulina; n = 213) and gray (Halichoerus grypus; n = 40) seals stranded in Denmark in the period 2014 to 2021 to determine the causes of mortality where feasible. The likelihood that human interactions did or might have contributed to the mortality was also assessed. Infection with lungworms, heartworms, gastrointestinal roundworms, and influenza virus was tested for each seal in the data. Parasitic bronchopneumonia was the most common cause of death in both harbor (n = 68) and gray (n = 8) seals, and significantly more juveniles than adults died as a result of parasitic infections in the harbor seal cohort. Starvation was also a major cause of death in juvenile seals. Cause of death, death class (found dead, euthanized, or culled), and whether human interactions played a role in mortality did not vary significantly between the two species. Traumatic causes of death, resulting from confirmed or probable human interactions, were associated with adult and subadult seals of both species. Culling was the cause of death for 13.6% of harbor seals and 17.5% of gray seals.
Incumbent clinker production practices fall short of meeting carbon-emission neutral targets, pressing the need to implement waste valorization approaches in cement plants to mitigate environmental impacts. However, there is a lack of knowledge on the future environmental performance of emerging waste-to-heat and fuel upcycling in clinker manufacturing. This study examines the prospective life cycle impacts of (1) solid recovered fuel (SRF) utilization and (2) on-site marine fuel production using integrated fluidized bed pyrolysis to substitute fossil fuels in clinker production and marine transportation. Environmental impacts are projected between 2025 and 2050 by applying learning effects in the foreground life cycle inventory and shared socioeconomic pathways (SSP1, SSP2), extended with the 1.9 W m−2 representative concentration pathway (SSP2-RCP1.9), in the background system. The highest decarbonization progress (−538.9 kg CO2-eq (t clinker)−1) is achieved under the SSP2-RCP1.9 development trajectory, driven by avoidance of emissions from waste management systems and converting biogenic carbon-rich municipal solid waste resources. The predicted CO2-eq impacts are found to be lower than the point source emission from raw meal calcination in several SSP scenarios, indicating that carbon-emission neutrality is attainable in combination with retrofitted carbon capture, utilization, and storage (CCUS) technologies. The assessment highlights the potential for burden shifting to other environmental impacts, e.g., particulate matter formation (+37.0 % by 2050), pointing to the need to evaluate additional pyrolysis oil upgrading and NOX emission mitigation strategies. Overall, synergizing waste pyrolysis with clinker production is found to be favourable due to (i) improved energy requirements, (ii) reduced fossil fuel use and impacts on climate change and ecosystem quality, and (iii) high potential for technological learning-driven environmental progress.
This paper highlights the urgent need to accelerate research and action on ocean carbon sinks through human intervention, known as Global Ocean Negative Carbon Emissions (Global-ONCE) Programme, as a vital strategy in global efforts to mitigate climate change. Achieving 'net zero' by 2050 cannot rely on emission reductions alone, emphasising the necessity of complementary approaches. Global-ONCE's mission extends beyond scientific exploration. It embodies a profound commitment to protecting and restoring blue carbon ecosystems, as well as implementing ocean-based solutions that are sustainable, equitable, and inclusive. Early Career Ocean Professionals (ECOPs) are at the heart of these efforts, and their innovative approaches, technical expertise, and passion make them indispensable leaders in advancing ONCE initiatives. ECOPs bridge the gap between science and society, playing a relevant role in integrating cutting-edge research, technological advancements, and community-driven action to address climate threats. By bringing together diverse perspectives and leveraging their interdisciplinary expertise, ECOPs ensure ONCE strategies are grounded in scientific rigour and practical feasibility. Through advocacy, education, and collaboration, ECOPs not only spearhead research and innovation but also inspire collective action to safeguard our oceans. This paper amplifies the critical role of ECOPs as agents of change and calls for a unified global commitment to harness the ocean's potential for a climate-resilient future.
Simulation-based analysis estimating both the energy requirement of the entire carbon capture process and the purity of the recovered CO 2 is scarce. The purity of the captured CO 2 is crucial as it must meet a specification before transportation, preventing phase change and damage to the transportation system. This study conducted 31,104 simulations of a monoethanolamine carbon capture plant treating measured flue gas from an existing cement production plant. After capture, the CO 2 is treated through a deoxygenation unit followed by a compression train to fulfill specific quality specifications. Based on the sensitivity analysis, the energy consumption of the post-treatment process decreased with increased purity downstream. Despite this, the total energy consumption was not affected. Moreover, after the two-step purification the CO 2 stream was able to successfully fulfill the specification for NO x, O 2, NH 3, Ar, CO, SO 2. However, failing to meet the H 2O concentration requirements of both considered specifications and the N 2 concentration specified for ship transport. Thus, increasing the post-treatment energy cost or standard adjustments is required for future applications.
Chalk reservoirs, due to their high porosity and very low permeability, represent one of the most interesting cases for engineering studies of carbonates. They exhibit complex fluid-rock interactions because of their reactive surfaces and dense porous medium. The reinjection of produced water is an attractive strategy for managing wastewater flow from oil wells. However, the complex composition of produced water, the reactive nature of carbonate rocks, and their low permeability create challenges related to permeability loss.
This study examines the stages of permeability change during core flooding experiments up to the point of complete clogging. A distinctive feature of this study is the presence of residual oil in the core samples, which simulates real reservoir conditions during produced water reinjection. The presence of residual oil is an additional factor influencing the change in core permeability, but there is no clear consensus in the research community on its impact on permeability during produced water injection.
All experiments were conducted in a core flooding system simulating well conditions in terms of pressure (170 bar) and temperature (70 ◦C). Produced water samples from the Dan field were used to replicate the chemical and thermodynamic processes occurring in a real well. The experiments identified three stages of permeability change: an initial increase in permeability (+12%), a period of pressure stabilization, and a subsequent decrease in permeability (− 8%) due to the formation of inorganic precipitates within the core channels.
The primary objective of the experiments is to investigate the relationship between permeability changes and the stages of reinjection, with a focus on the effects of residual oil. The study focuses on identifying the processes occurring up to the point of complete clogging, considering the impact of residual oil saturation in the chalk core samples. Image analysis using scanning electron microscopy, particle size measurement with a zeta-potential meter, and thermodynamic scale formation modeling with ScaleCERE software were employed to explain these processes.
Three stages of permeability change were identified during the injection of 200 pore volumes of produced water: increased permeability (+12%), pressure stabilization, and decreased permeability (− 8%). The positive influence of residual oil saturation on the filtration and storage properties of the reservoir was established, due to the mobilization of chalk core particles. Additionally, the theory of core channel clogging during the reinjection of formation water by the formation of inorganic precipitates within the channels was confirmed.
Understanding the causes of permeability reduction that occurred during the stage of permeability decrease enables the development of water purification methods specifically targeted at the causes of rock clogging. Predicting the process of injecting a mixture of produced and seawater will help in interpreting the data during disposal operations by injecting formation water into an injection well, and it will allow for the selection of effective measures to mitigate the impact on the reservoir.
Mobilization of residual oil droplets is the key process for enhanced oil recovery. Visualization of the droplet movement at a pore level provides insights on the underlying physical mechanisms. We couple a microfluidic droplet generator and a thin glass capillary to study the movement of oil droplets under salinity gradients with visualization of individual droplet movements. The driving forces that affect the movement of the droplets are discussed. We demonstrate experimentally that oil droplets in micro-confined channels can be mobilized and move against pressure under the concentration gradients of dissolved salts. The gradient-driven movement can be strong enough to drive a droplet through a narrow constriction in the middle of the capillary channel. The droplet movement can be understood by combining a Marangoni stress due to surfactant redistribution, electrostatic interaction and diffusiophoresis. This suggests that the abrupt change of salinity may be one of the physical mechanisms of smart waterflooding.
Large volumes of produced water are being discharged globally as byproducts of oil production. Commercial production chemicals are conventionally needed to avoid problems such as bacterial growth, pipe corrosion, and oil/water separation issues. These chemicals will partition between oil and water phases and may affect both treatment processes and the environmental impact when water is discharged to the ocean after treatment. Capillary zone electrophoresis is used to measure partitioning coefficients of oilfield chemicals when these are dissolved in the water phase and in contact with either octanol or crude oil. The technique is fast and, due to simplicity, could have merits as on-site assessment of the partition coefficient for direct assessment of the fate of chemicals. The method was first qualified by estimating partitioning coefficients of aliphatic carboxylic acids and chemicals with a molecular structure similar to those of some production chemicals. Subsequently, the coefficients were determined for two different commercial corrosion inhibitors and a biocide that are used in the oilfield as production chemicals. The results showed that the chemicals predominantly preferred to remain in the water phase after contact with either octanol or crude oil. The partitioning coefficients log(p) spanned between −0.36 and −1.68 in the case of water/octanol contact and between 2.68 and −1.41 in the case of water/crude oil contact. One of the corrosion inhibitors exhibited a significant difference in the partitioning depending on whether the organic phase was octanol or crude oil. The chemical had a preference for the water phase in the case of the former but a preference for the crude oil phase in the case of the latter. The result demonstrates that it makes it challenging to evaluate the use of partitioning coefficients for oilfield applications.