This paper presents experimental measurements of beaching times for buoyant microplastic particles released, both in the pre-breaking region and within the surf zone. The beaching times are used to quantify cross-shore Lagrangian transport velocities of the microplastics. Prior to breaking the particles travel onshore with a velocity close to the Lagrangian fluid particle velocity, regardless of particle characteristics. In the surf zone the Lagrangian velocities of the microplastics increase and become closer to the wave celerity. Furthermore, it is demonstrated that particles having low Dean numbers (dimensionless fall velocity) are transported at higher mean velocities, as they have a larger tendency to be at the free-surface relative to particles with higher Dean numbers. An empirical relation is formulated for predicting the cross-shore Lagrangian transport velocities of buoyant microplastic particles, valid for both non-breaking and breaking irregular waves. The expression matches the present experiments well, in addition to two prior studies.
Ship-source pollution represents a threat to the environment, regardless of where it occurs. The European Union has been developing standards that aim to counter accidental, operational and intentional pollution in the waters under its member-state's jurisdiction. However, and precisely because marine pollution knows no boundaries, the EU is not coy in contemplating what ships do beyond waters under the sovereignty of its member states. This article analyzes the international legality of EU claims to port state jurisdiction over ship-source pollution. It demonstrates that port state jurisdiction is today not only a means to ensure compliance with international standards but also a means to unilaterally enforce more stringent environmental standards.
The offshore oilfields in the North Sea area are increasingly employed for projects beyond oil production, like carbon capture and storage (CCS). Still, the fossil fuel production from mature fields is significant. It has raised environmental concerns associated with discharging produced waters (PW) and drilling mud into the sea. These discharges, which may be highly saline and contain production chemicals, vary significantly in metals and particulate content. Due to density and release depth, the plume is assumed to sink towards the seafloor. Also, a single oilfield can input up to 7.5 tons of Ba, 675 kg of Fe, and 619 kg of P into the water column through PW. Therefore, this study investigates the impact of these discharges on seafloor sediments around two Danish oilfields, assesses the mobility of metals within these sediments, and evaluates the environmental status. PW samples were collected at the discharge outlets from the platforms. Sediment cores were taken near the two oil platforms and from control sites. Using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and an optimized BCR sequential extraction, we analyzed the composition and distribution of 24 elements in sediment samples. The results revealed significant differences in total extracted concentrations between sediments near the platforms and those from distant locations and stratigraphically older samples, with relevant levels of Br, Ba, and Sn near the platforms (averaged 14, 27, and 0.1 ppb, respectively). Sediment quality indices showed considerable enrichment and geo-accumulation of toxic metals, particularly at one of the platform sites. However, cumulative indices did not display significant pollution anomalies. Therefore, our findings suggest that oil extraction activities may increase the availability of toxic metals in nearby sediments, potentially impacting marine ecosystems.
Determination of coverage and thickness of marine growth is a useful tool for determining structural loads and drags on marine structures and ships. In this work, we present an algorithmic program based on sonar and optical camera measurements, that estimates both the coverage and thickness of marine-fouling on off-shore structures. The marine-fouling composition is estimated using a Deep-Neural Network, trained using supervised methods, which can distinguish between hard/soft fouling species and the background water and structural components. The marine-fouling thickness is estimated using an HF Forward Looking Sonar, which is applied as a sensitive ultrasonic thickness gauge, when combined with a thickness measurement algorithm. Combined the measurements provide a localized estimate of the marine-fouling coverage and loadings across the structural surfaces, which can be used for automatic inspection evaluation and mission planning.
Crude oil and cadmium (Cd) are common pollutants in Ghana's coastal ecosystems, where the cyanobacterial phytoplankton Synechococcus sp. serves as the primary producer and forms the base of the marine food web alongside small grazers. We hypothesized that cadmium and crude oil would disrupt microbial community structure and function, with the strongest effects under combined exposure. This study investigates the toxic effects of Oil (2 mL L−1), Cd (4.4 μg L−1), and their combined impact (Cd + Oil) on functional groups within the coastal microbial community, including Synechococcus sp., heterotrophic bacteria, nanoflagellates, eukaryotic phytoplankton, ciliates, and dinoflagellates, as well as on copepod nauplii and copepodite development during six-day incubations. We observed acute toxic effects on heterotrophic ciliates and dinoflagellates, with >50 % reductions in abundance within 6 h and a marked decrease in diversity. Phytoplankton showed growth within the first 24 h due to nutrient replenishment from the protist decay, however, their growth continued to decline after 24 h, with Synechococcus being particularly sensitive to Cd and less affected by Oil. In contrast, heterotrophic bacteria increased in abundance across all treatments, likely benefiting from organic matter released during phytoplankton decay and their high adaptability. Notably, the bacterial genera Marivivens and Rhodovulum became dominant mainly in the Oil-amended treatments. Overall, the microbial groups exhibited diverse responses to the pollutants, with the combined Cd + Oil treatment exerting the strongest negative effects, while crude oil alone had the least impact. These findings highlight the vulnerability of tropical microbial food webs, typically dominated by Synechococcus and microbial grazers, to combined pollutant stress, with potential cascading effects on higher trophic levels and coastal ecosystem productivity. This highlights the need for comprehensive monitoring and conservation efforts in these globally significant, yet understudied, regions.
Chalk reservoirs, due to their high porosity and very low permeability, represent one of the most interesting cases for engineering studies of carbonates. They exhibit complex fluid-rock interactions because of their reactive surfaces and dense porous medium. The reinjection of produced water is an attractive strategy for managing wastewater flow from oil wells. However, the complex composition of produced water, the reactive nature of carbonate rocks, and their low permeability create challenges related to permeability loss.
This study examines the stages of permeability change during core flooding experiments up to the point of complete clogging. A distinctive feature of this study is the presence of residual oil in the core samples, which simulates real reservoir conditions during produced water reinjection. The presence of residual oil is an additional factor influencing the change in core permeability, but there is no clear consensus in the research community on its impact on permeability during produced water injection.
All experiments were conducted in a core flooding system simulating well conditions in terms of pressure (170 bar) and temperature (70 ◦C). Produced water samples from the Dan field were used to replicate the chemical and thermodynamic processes occurring in a real well. The experiments identified three stages of permeability change: an initial increase in permeability (+12%), a period of pressure stabilization, and a subsequent decrease in permeability (− 8%) due to the formation of inorganic precipitates within the core channels.
The primary objective of the experiments is to investigate the relationship between permeability changes and the stages of reinjection, with a focus on the effects of residual oil. The study focuses on identifying the processes occurring up to the point of complete clogging, considering the impact of residual oil saturation in the chalk core samples. Image analysis using scanning electron microscopy, particle size measurement with a zeta-potential meter, and thermodynamic scale formation modeling with ScaleCERE software were employed to explain these processes.
Three stages of permeability change were identified during the injection of 200 pore volumes of produced water: increased permeability (+12%), pressure stabilization, and decreased permeability (− 8%). The positive influence of residual oil saturation on the filtration and storage properties of the reservoir was established, due to the mobilization of chalk core particles. Additionally, the theory of core channel clogging during the reinjection of formation water by the formation of inorganic precipitates within the channels was confirmed.
Understanding the causes of permeability reduction that occurred during the stage of permeability decrease enables the development of water purification methods specifically targeted at the causes of rock clogging. Predicting the process of injecting a mixture of produced and seawater will help in interpreting the data during disposal operations by injecting formation water into an injection well, and it will allow for the selection of effective measures to mitigate the impact on the reservoir.
From the process control point of view, any reliable and online Oil-in-Water (OiW) measurement could provoke a brand new control paradigm for produced water treatment. However, the real-time OiW monitoring is still an open and ad-hoc situation in recent decades. The fundamental issue, ie, the OiW measurement is methodology dependent, leads to numerous challenges, such as (i) how to verify the reliability and accuracy of a specific methodology/instrument; (ii) how to handle and interpret the measured data in a most objective manner; and (iii) how to keep a cost-effective on-site calibration and maintenance under the harsh offshore conditions etc. The paper reports our latest achievements and observations in usage of fluorescence- and microscopybased OiW monitoring technologies for advanced Produced Water Treatment (PWT) control and evaluation, particularly by focusing on the de-oiling hydrocyclone installations.
Underwater radiated noise (URN) from ship propellers has attracted increasing interest in recent years due to its adverse environmental effects on marine life and their communication channels. The environmental concern to reduce shipping noise and the industrial requirements for faster computational tools are driving factors that promote research in the specialized domain of hydroacoustics. This thesis deals with the development of such a computationally efficient numerical tool, which can be used in the prediction of underwater radiated noise in the early design phase of propellers.
The numerical model is developed with two major objectives – versatility in assessing the relative contributions from the major propeller-noise generating mechanisms, and rapidity in prediction of overall noise behaviour. It uses the Farassat-1A solid-FWH formulation of the Ffowcs-Williams- Hawkings equation by defining equivalent acoustic sources on the propeller blade, sheet cavity and tip vortex cavity surfaces. In particular, the application of the solid-FWH formulation to the tip vortex cavity model is the major novelty in this thesis.
The hydrodynamic flow solution is obtained from a potential flow based solver ESPPRO, which includes analytical models of sheet cavitation and tip vortex cavitation. The hydroacoustic numerical model developed within this thesis, DoLPHiN, is a Python-based code that is primarily designed to accept input from ESPPRO; but during the research, the code has also been adapted to read input from the commercial, finite-volume-based Navier-Stokes solver, STAR-CCM+.
The numerical model implementations are verified through analytical case studies for simple geometrical shapes, such as a pulsating sphere and an oscillating cylindrical cavity. The verification study is further extended for propeller geometries by identifying approximate reference solutions in simplified operating conditions. The numerical tool is validated for industrial application through comparison of its noise prediction with model-scale and full-scale noise measurements. Specific characteristics of the propeller noise spectrum are identified in order to evaluate its noise prediction capabilities. The uncertainty factors involved when validating with experimental measurements are also explored in detail. Furthermore, a design study is presented, which shows potential use of the numerical tool in practical propeller design and optimization applications.
Plastic litter is introduced into the oceans from land-based sources located in many countries around the world. Marine plastic pollution may therefore be attributable to multiple states, resulting in shared state responsibility. This article discusses the issue of shared state responsibility for land-based marine plastic pollution by examining (i) primary rules of international law concerning the prevention of land-based marine plastic pollution; (ii) secondary rules of international law on this subject; and (iii) possible ways of strengthening the primary rules. It concludes that the barrier for the invocation of state responsibility may become higher in cases of shared state responsibility. Three cumulative solutions to this problem are proposed: elaborating the obligation of due diligence, strengthening compliance procedures, and interlinking regimes governing the marine environment and international watercourses.
The capacity to act as a port state in international law is best described by the specific powers exercised over foreign ships, namely inspection, detention, expulsion or request of any type of information prior to the entry into the port. Many of these powers are explicitly attributed to the state in multilateral instruments, whereby the flag state consents to having its ships subject to the jurisdiction of the port state. Notwithstanding the consensus around the complementary nature of port state jurisdiction with respect to certain obligations of the flag state, the port state is not limited to fulfilling a secondary role. This is especially visible in the prevention, reduction and control of ship-source pollution, where some port states have not hesitated in acting regardless of an expressed consent by the flag state to the rule or standard being applied with the support of port powers. Not only do port states use more stringent enforcement powers to ensure that international treaties are effective, but they also prescribe novel rules and standards upon any foreign ship that approaches the port, often as a means of breaking an international negotiation deadlock. This study discusses the international legal basis for such unilateral jurisdiction by analyzing the principles of state jurisdiction under the dichotomy parochial/cosmopolitan. By interpreting the stated and implicit purposes of port state actions under that dichotomy, this study proposes that states are finding a legal ground to act based on certain legal functions they fulfill in the international legal order. This argument puts into perspective the assumed self-sufficiency of territoriality and shows how unilateralism may also serve to seek to set universally applicable norms.