The impact of the growing cruise ship industry on air quality levels was investigated at the port of Copenhagen, Denmark. In 2018, 345 cruise ships visited Copenhagen, emitting 291 tons of NOx near the city centre. A spatiotemporal cruise ship emission inventory was developed for 2018 based on port list information, engine data, main and auxiliary engine power functions, and NOx emission factors, and was implemented in the OML-Multi atmospheric dispersion model. Evident plume effects from the cruise ships, which were traced by introducing the concept of likely concentration contribution, were obtained in the modelled and measured concentrations at Langelinie Quay, which is the busiest cruise ship terminal in Copenhagen port. Hourly peak values of NOx well above 200 μg m−3 were obtained at the top of a residential building at Langelinie Quay. The emissions from cruise ships were increasing the annual concentration of NO2 in the port area by up to 31% at ground level, and 86% 50 m above the ground in comparison to the urban background level. No exceedance of the European annual limit value of NO2 was obtained. The short-term impact of cruise ships was more pronounced with local exceedances of the hourly European limit value for NO2. Increasing cruise ship activity in Copenhagen port leads to air quality deterioration on short time scales with implications for human health.
The International Ballast Water Management (BWM) Convention entered into force in September 2017. In the convention, the International Maritime Organization (IMO) required two options: ballast water exchange (BWE) standard D-1, and ballast water performance standard D-2 which required ballast water treatment systems (BWTSs). We explored the impact of policy on the utilization of BWTSs by examining IMO Type Approval records and country-level databases in the United States and Australia. In December 2018, 65 BWTSs had IMO Type Approval and 13 had US Coast Guard approval. The majority of vessels with BWTSs had either electrolytic or UV treatment systems (Australia, 84%; USA, 89%). From 2016 to 2017, both countries experienced an increase in the percentage of vessels with BWTS, vessels utilizing BWTS, and total ballast discharge treated with BWTS. Based on this analysis, shipowners appear to primarily rely on two treatment technologies in Australia and the United States to meet compliance.
This paper presents a wave flume investigation of beaching times for buoyant microplastic particles dropped at various distance from the shoreline. The beaching times are used to quantify the cross-shore Lagrangian transport velocities of the microplastic particles. Results show that prior to breaking, there is little dependence on particle characteristics (e.g. their rise velocity), and the particles travel onshore with a velocity close to the Lagrangian fluid particle velocity. In the surf zone the Lagrangian transport velocities of the microplastic particles increase significantly, becoming closer to the wave celerity. Additionally, particle characteristics become important, as particles with low Dean numbers (high rise velocity) have a greater tendency to be captured by surface rollers relative to particles with larger Dean numbers (lower rise velocity). An empirical relation is formulated for predicting the cross-shore Lagrangian transport velocities of buoyant microplastic particles. The expression matches the present experiments well and is valid for both non-breaking and breaking irregular waves. These findings help in understanding the accumulation of microplastics at beaches due to the surf-zone processes, especially for buoyant particles.
Despite the relatively rich literature on the omnipresence of microplastics in marine environments, the current status and ecological impacts of microplastics on global Marine Protected Areas (MPAs) are still unknown. Their ubiquitous occurrence, increasing volume, and ecotoxicological effects have made microplastic an emerging marine pollutant. Given the critical conservation roles of MPAs that aim to protect vulnerable marine species, biodiversity, and resources, it is essential to have a comprehensive overview of the occurrence, abundance, distribution, and characteristics of microplastics in MPAs including their buffer zones. Here, extensive data were collected and screened based on 1565 peer-reviewed literature from 2017 to 2020, and a GIS-based approach was applied to improve the outcomes by considering boundary limits. Microplastics in seawater samples were verified within the boundaries of 52 MPAs; after including the buffer zones, 1/3 more (68 MPAs) were identified as contaminated by microplastics. A large range of microplastic levels in MPAs was summarized based on water volume (0–809,000 items/m 3) or surface water area (21.3–1,650,000,000 items/km 2), which was likely due to discrepancy in sampling and analytical methods. Fragment was the most frequently observed shape and fiber was the most abundant shape. PE and PP were the most common and also most abundant polymer types. Overall, 2/3 of available data reported that seawater microplastic levels in MPAs were higher than 12,429 items/km 2, indicating that global MPAs alone cannot protect against microplastic pollution. The current limitations and future directions were also discussed toward the post-2020 Global Biodiversity Framework goals.
Results from life cycle assessment (LCA) studies are sensitive to modeling choices and data used in building the underlying model. This is also relevant for the case of fisheries and LCAs of fish products. Fisheries' product systems show both multifunctionality because of the simultaneous co-catch of multiple species and potential constraints to supply due to natural stock limits or socially established limits such as quota systems. The performance of fisheries also varies across seasons, locations, vessels, and target species. In this study, we investigate the combined effect of modeling choices and variability on the uncertainty of LCA results of fish products. We use time series data from official Danish statistics for catch and fuel use of several fisheries disaggregated using a top-down procedure. We apply multiple modeling approaches with different assumptions regarding the type of partitioning, substitution, and constraints. The analysis demonstrates that, in the presence of relevant multifunctionality, the results are substantially affected by the modeling approach chosen. These findings are robust across years and fisheries, indicating that modeling choices contribute to uncertainty more than the variability in fishing conditions. We stress the need for a more careful alignment of research questions and methods for LCA studies of fisheries and recommend a very transparent statement of assumptions, combined with uncertainty and sensitivity analysis. This article met the requirements for a gold-gold data openness badge described at http://jie.click.badges.
Mobilization of residual oil droplets is the key process for enhanced oil recovery. Visualization of the droplet movement at a pore level provides insights on the underlying physical mechanisms. We couple a microfluidic droplet generator and a thin glass capillary to study the movement of oil droplets under salinity gradients with visualization of individual droplet movements. The driving forces that affect the movement of the droplets are discussed. We demonstrate experimentally that oil droplets in micro-confined channels can be mobilized and move against pressure under the concentration gradients of dissolved salts. The gradient-driven movement can be strong enough to drive a droplet through a narrow constriction in the middle of the capillary channel. The droplet movement can be understood by combining a Marangoni stress due to surfactant redistribution, electrostatic interaction and diffusiophoresis. This suggests that the abrupt change of salinity may be one of the physical mechanisms of smart waterflooding.
The latest IPCC report on Ocean and Cryosphere in a Changing Climate, which builds upon previous IPCC's reports, established a causal link between anthropogenic impacts and ocean acidification, by noting a significant decrease in the Ocean's uptake of CO2, with consequent damage to Earth's ecosystems, which in turn has traceable repercussions on the Arctic Ocean and then from the Arctic to the Planet Earth. The impact of ocean acidification is not only in the biological ecosystem but also on human activities, such as livelihood, food security, socio-economic security and developing communities. However, who can possibly be held ethically/legally responsible for ocean acidification from a climate justice perspective? Since what happens in the Arctic does not stay there, a more systematic law and policy approach to study options and responses in a multi-level, climate-ethical, global perceptive is needed. This paper sheds light on the legal responses available at global, regional and national levels to ocean acidification in a law of the sea and ocean context, both in the Arctic and from the Arctic. The gaps in legal and policy responses in connection to the ethical climate component will be identified. It will shed light on the planetary limits that humanity needs to stay within in order to maintain the future of the Earth. Since it touches upon questions of legal responsibility, on who is responsible for ocean acidification, it will connect to the “supply side” of fossil fuels production and global extraction projects causing anthropogenic CO2 emissions, one of the major causes of ocean acidification. It will also identify which actors, be they "officials" or "non-officials" (such as international organizations, states, regional institutes, Arctic citizens or even forums) should be held ethically responsible, and who should take action.
This study investigates the complex and still insufficiently understood interactions between ocean currents and offshore wind farms (OWFs), with a focus on local-scale hydrodynamic effects near individual wind turbine foundations. Despite growing interest in the environmental impacts of OWFs, empirical field data on local-scale current dynamics within wind farms remain sparse. This technical report describes the results from a field campaign, which was conducted within the Anholt OWF in the Kattegat over a 9-day period in August 2024.
The shipping industry faces huge challenges with regard to improving its environmental performance. The current regulatory approach has not been successful. Public and private actors increasingly rely on partnerships. The literature on partnerships for sustainability has contributed to a better conceptualisation of the subject. However, less is known about the processes and the outcomes of the partnerships as well as interactions between partnerships. This paper aims to improve the understanding of how partnerships contribute to developing cleaner technologies in the Danish shipping industry. Two partnerships have been analysed: Partnership for Cleaner Shipping and the Green Ship of the Future. Participation, scope and division of roles among partners have influenced both partnerships. Furthermore, both partnerships have developed organisational forms that proved to overcome the tensions in traditional partnerships, between open and information-based networking on the one side and closed and development-oriented collaboration on the other side.
Chalk reservoirs, due to their high porosity and very low permeability, represent one of the most interesting cases for engineering studies of carbonates. They exhibit complex fluid-rock interactions because of their reactive surfaces and dense porous medium. The reinjection of produced water is an attractive strategy for managing wastewater flow from oil wells. However, the complex composition of produced water, the reactive nature of carbonate rocks, and their low permeability create challenges related to permeability loss.
This study examines the stages of permeability change during core flooding experiments up to the point of complete clogging. A distinctive feature of this study is the presence of residual oil in the core samples, which simulates real reservoir conditions during produced water reinjection. The presence of residual oil is an additional factor influencing the change in core permeability, but there is no clear consensus in the research community on its impact on permeability during produced water injection.
All experiments were conducted in a core flooding system simulating well conditions in terms of pressure (170 bar) and temperature (70 ◦C). Produced water samples from the Dan field were used to replicate the chemical and thermodynamic processes occurring in a real well. The experiments identified three stages of permeability change: an initial increase in permeability (+12%), a period of pressure stabilization, and a subsequent decrease in permeability (− 8%) due to the formation of inorganic precipitates within the core channels.
The primary objective of the experiments is to investigate the relationship between permeability changes and the stages of reinjection, with a focus on the effects of residual oil. The study focuses on identifying the processes occurring up to the point of complete clogging, considering the impact of residual oil saturation in the chalk core samples. Image analysis using scanning electron microscopy, particle size measurement with a zeta-potential meter, and thermodynamic scale formation modeling with ScaleCERE software were employed to explain these processes.
Three stages of permeability change were identified during the injection of 200 pore volumes of produced water: increased permeability (+12%), pressure stabilization, and decreased permeability (− 8%). The positive influence of residual oil saturation on the filtration and storage properties of the reservoir was established, due to the mobilization of chalk core particles. Additionally, the theory of core channel clogging during the reinjection of formation water by the formation of inorganic precipitates within the channels was confirmed.
Understanding the causes of permeability reduction that occurred during the stage of permeability decrease enables the development of water purification methods specifically targeted at the causes of rock clogging. Predicting the process of injecting a mixture of produced and seawater will help in interpreting the data during disposal operations by injecting formation water into an injection well, and it will allow for the selection of effective measures to mitigate the impact on the reservoir.