Chalk reservoirs, due to their high porosity and very low permeability, represent one of the most interesting cases for engineering studies of carbonates. They exhibit complex fluid-rock interactions because of their reactive surfaces and dense porous medium. The reinjection of produced water is an attractive strategy for managing wastewater flow from oil wells. However, the complex composition of produced water, the reactive nature of carbonate rocks, and their low permeability create challenges related to permeability loss.
This study examines the stages of permeability change during core flooding experiments up to the point of complete clogging. A distinctive feature of this study is the presence of residual oil in the core samples, which simulates real reservoir conditions during produced water reinjection. The presence of residual oil is an additional factor influencing the change in core permeability, but there is no clear consensus in the research community on its impact on permeability during produced water injection.
All experiments were conducted in a core flooding system simulating well conditions in terms of pressure (170 bar) and temperature (70 ◦C). Produced water samples from the Dan field were used to replicate the chemical and thermodynamic processes occurring in a real well. The experiments identified three stages of permeability change: an initial increase in permeability (+12%), a period of pressure stabilization, and a subsequent decrease in permeability (− 8%) due to the formation of inorganic precipitates within the core channels.
The primary objective of the experiments is to investigate the relationship between permeability changes and the stages of reinjection, with a focus on the effects of residual oil. The study focuses on identifying the processes occurring up to the point of complete clogging, considering the impact of residual oil saturation in the chalk core samples. Image analysis using scanning electron microscopy, particle size measurement with a zeta-potential meter, and thermodynamic scale formation modeling with ScaleCERE software were employed to explain these processes.
Three stages of permeability change were identified during the injection of 200 pore volumes of produced water: increased permeability (+12%), pressure stabilization, and decreased permeability (− 8%). The positive influence of residual oil saturation on the filtration and storage properties of the reservoir was established, due to the mobilization of chalk core particles. Additionally, the theory of core channel clogging during the reinjection of formation water by the formation of inorganic precipitates within the channels was confirmed.
Understanding the causes of permeability reduction that occurred during the stage of permeability decrease enables the development of water purification methods specifically targeted at the causes of rock clogging. Predicting the process of injecting a mixture of produced and seawater will help in interpreting the data during disposal operations by injecting formation water into an injection well, and it will allow for the selection of effective measures to mitigate the impact on the reservoir.
The capacity to act as a port state in international law is best described by the specific powers exercised over foreign ships, namely inspection, detention, expulsion or request of any type of information prior to the entry into the port. Many of these powers are explicitly attributed to the state in multilateral instruments, whereby the flag state consents to having its ships subject to the jurisdiction of the port state. Notwithstanding the consensus around the complementary nature of port state jurisdiction with respect to certain obligations of the flag state, the port state is not limited to fulfilling a secondary role. This is especially visible in the prevention, reduction and control of ship-source pollution, where some port states have not hesitated in acting regardless of an expressed consent by the flag state to the rule or standard being applied with the support of port powers. Not only do port states use more stringent enforcement powers to ensure that international treaties are effective, but they also prescribe novel rules and standards upon any foreign ship that approaches the port, often as a means of breaking an international negotiation deadlock. This study discusses the international legal basis for such unilateral jurisdiction by analyzing the principles of state jurisdiction under the dichotomy parochial/cosmopolitan. By interpreting the stated and implicit purposes of port state actions under that dichotomy, this study proposes that states are finding a legal ground to act based on certain legal functions they fulfill in the international legal order. This argument puts into perspective the assumed self-sufficiency of territoriality and shows how unilateralism may also serve to seek to set universally applicable norms.
Ship-source pollution represents a threat to the environment, regardless of where it occurs. The European Union has been developing standards that aim to counter accidental, operational and intentional pollution in the waters under its member-state's jurisdiction. However, and precisely because marine pollution knows no boundaries, the EU is not coy in contemplating what ships do beyond waters under the sovereignty of its member states. This article analyzes the international legality of EU claims to port state jurisdiction over ship-source pollution. It demonstrates that port state jurisdiction is today not only a means to ensure compliance with international standards but also a means to unilaterally enforce more stringent environmental standards.
The offshore oilfields in the North Sea area are increasingly employed for projects beyond oil production, like carbon capture and storage (CCS). Still, the fossil fuel production from mature fields is significant. It has raised environmental concerns associated with discharging produced waters (PW) and drilling mud into the sea. These discharges, which may be highly saline and contain production chemicals, vary significantly in metals and particulate content. Due to density and release depth, the plume is assumed to sink towards the seafloor. Also, a single oilfield can input up to 7.5 tons of Ba, 675 kg of Fe, and 619 kg of P into the water column through PW. Therefore, this study investigates the impact of these discharges on seafloor sediments around two Danish oilfields, assesses the mobility of metals within these sediments, and evaluates the environmental status. PW samples were collected at the discharge outlets from the platforms. Sediment cores were taken near the two oil platforms and from control sites. Using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and an optimized BCR sequential extraction, we analyzed the composition and distribution of 24 elements in sediment samples. The results revealed significant differences in total extracted concentrations between sediments near the platforms and those from distant locations and stratigraphically older samples, with relevant levels of Br, Ba, and Sn near the platforms (averaged 14, 27, and 0.1 ppb, respectively). Sediment quality indices showed considerable enrichment and geo-accumulation of toxic metals, particularly at one of the platform sites. However, cumulative indices did not display significant pollution anomalies. Therefore, our findings suggest that oil extraction activities may increase the availability of toxic metals in nearby sediments, potentially impacting marine ecosystems.
Taking offspring in a problem of ship emission reduction by exhaust gas recirculation control for large diesel engines, an underlying generic estimation challenge is formulated as a problem of joint state and parameter estimation for a class of multiple-input single-output Hammerstein systems with first-order dynamics, sensor delay, and a bounded time-varying parameter in the nonlinear part. This brief suggests a novel scheme for this estimation problem that guarantees exponential convergence to an interval that depends on the sensitivity of the system. The system is allowed to be nonlinear, parameterized, and time dependent, which are characteristics of the industrial problem we study. The approach requires the input nonlinearity to be a sector nonlinearity in the time-varying parameter. Salient features of the approach include simplicity of design and implementation. The efficacy of the adaptive observer is shown on simulated cases, on tests with a large diesel engine on test bed, and on tests with a container vessel.
The offshore de-oiling process is a vital part of current oil recovery, as it separates the profitable oil from water and ensures that the discharged water contains as little of the polluting oil as possible. With the passage of time, there is an increase in the water fraction in reservoirs that adds to the strain put on these facilities, and thus larger quantities of oil are being discharged into the oceans, which has in many studies been linked to negative effects on marine life. In many cases, such installations are controlled using non-cooperative single objective controllers which are inefficient in handling fluctuating inflows or complicated operating conditions. This work introduces a model-based robust H ∞ control solution that handles the entire de-oiling system and improves the system’s robustness towards fluctuating flow thereby improving the oil recovery and reducing the environmental impacts of the discharge. The robust H ∞ control solution was compared to a benchmark Proportional-Integral-Derivative (PID) control solution and evaluated through simulation and experiments performed on a pilot plant. This study found that the robust H ∞ control solution greatly improved the performance of the de-oiling process.
There has been a continued increase in the load on the current offshore oil and gas de-oiling systems that generally consist of three-phase gravity separators and de-oiling hydrocyclones. Current feedback control of the de-oiling systems is not done based on de-oiling efficiency, mainly due to lack of real-time monitoring of oil-in-water concentration, and instead relies on an indirect method using pressure drop ratio control. This study utilizes a direct method where a real-time fluorescence-based instrument was used to measure the transient efficiency of a hydrocyclone combined with an upstream gravity separator. Two control strategies, a conventional PID control structure and an H ∞ robust control structure, both using conventional feedback signals were implemented, and their efficiency was tested during severely fluctuating flow rates. The results show that the direct method can measure the system's efficiency in real time. It was found that the efficiency of the system can be misleading, as fluctuations in the feed flow affect the inlet concentration more than the outlet oil concentration, which can lead to a discharge of large oil quantities into the ocean.
This article is a feasibility study on using fluorescence-based oil-in-water (OiW) monitors for on-line dynamic efficiency measurement of a deoiling hydrocyclone. Dynamic measurements are crucial in the design and validation of dynamic models of the hydrocyclones, and to our knowledge, no dynamic OiW analysis of hydrocyclones has been carried out. Previous studies have extensively studied the steady state efficiency perspective of hydrocyclones, and have related them to different key parameters, such as the pressure drop ratio (PDR), inlet flow rate, and the flow spill. Through our study, we were able to measure the dynamics of the hydrocyclone's efficiency (ϵ) response to step changes in the inlet flow rate with high accuracy. This is a breakthrough in the modelling, control, and monitoring of hydrocyclones.
The goal of this paper is to introduce and design a cost-effective Oil-in-Water (OiW) measuring instrument, which will be investigated for its value in increasing the efficiency of a deoiling hydrocyclone. The technique investigated is based on Electrical Resistivity Tomography (ERT), whose basic principle is to measure the resistivity of substances from multiple electrodes and from these measurements create a 2-D image of the oil and gas component in the water. This technique requires the measured components to have different electrical resistances, such as seawater which has a lower electrical resistance than hydrocarbon oil and gas. This work involves construction of a pilot plant, for testing the feasibility of ERT for OiW measurements, and further exploring if this measured signal can be applied as a reliable feedback signal in optimization of the hydrocyclone's efficiency. Different algorithms for creating 2-D images and the feasibility of estimating OiW concentrations are studied and evaluated. From both steady state and continuous laminate flow perspectives, with respect to the objective which is to use this measurement for feedback control purposes.
Plastic litter is introduced into the oceans from land-based sources located in many countries around the world. Marine plastic pollution may therefore be attributable to multiple states, resulting in shared state responsibility. This article discusses the issue of shared state responsibility for land-based marine plastic pollution by examining (i) primary rules of international law concerning the prevention of land-based marine plastic pollution; (ii) secondary rules of international law on this subject; and (iii) possible ways of strengthening the primary rules. It concludes that the barrier for the invocation of state responsibility may become higher in cases of shared state responsibility. Three cumulative solutions to this problem are proposed: elaborating the obligation of due diligence, strengthening compliance procedures, and interlinking regimes governing the marine environment and international watercourses.