The offshore oilfields in the North Sea area are increasingly employed for projects beyond oil production, like carbon capture and storage (CCS). Still, the fossil fuel production from mature fields is significant. It has raised environmental concerns associated with discharging produced waters (PW) and drilling mud into the sea. These discharges, which may be highly saline and contain production chemicals, vary significantly in metals and particulate content. Due to density and release depth, the plume is assumed to sink towards the seafloor. Also, a single oilfield can input up to 7.5 tons of Ba, 675 kg of Fe, and 619 kg of P into the water column through PW. Therefore, this study investigates the impact of these discharges on seafloor sediments around two Danish oilfields, assesses the mobility of metals within these sediments, and evaluates the environmental status. PW samples were collected at the discharge outlets from the platforms. Sediment cores were taken near the two oil platforms and from control sites. Using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and an optimized BCR sequential extraction, we analyzed the composition and distribution of 24 elements in sediment samples. The results revealed significant differences in total extracted concentrations between sediments near the platforms and those from distant locations and stratigraphically older samples, with relevant levels of Br, Ba, and Sn near the platforms (averaged 14, 27, and 0.1 ppb, respectively). Sediment quality indices showed considerable enrichment and geo-accumulation of toxic metals, particularly at one of the platform sites. However, cumulative indices did not display significant pollution anomalies. Therefore, our findings suggest that oil extraction activities may increase the availability of toxic metals in nearby sediments, potentially impacting marine ecosystems.
Chalk reservoirs, due to their high porosity and very low permeability, represent one of the most interesting cases for engineering studies of carbonates. They exhibit complex fluid-rock interactions because of their reactive surfaces and dense porous medium. The reinjection of produced water is an attractive strategy for managing wastewater flow from oil wells. However, the complex composition of produced water, the reactive nature of carbonate rocks, and their low permeability create challenges related to permeability loss.
This study examines the stages of permeability change during core flooding experiments up to the point of complete clogging. A distinctive feature of this study is the presence of residual oil in the core samples, which simulates real reservoir conditions during produced water reinjection. The presence of residual oil is an additional factor influencing the change in core permeability, but there is no clear consensus in the research community on its impact on permeability during produced water injection.
All experiments were conducted in a core flooding system simulating well conditions in terms of pressure (170 bar) and temperature (70 ◦C). Produced water samples from the Dan field were used to replicate the chemical and thermodynamic processes occurring in a real well. The experiments identified three stages of permeability change: an initial increase in permeability (+12%), a period of pressure stabilization, and a subsequent decrease in permeability (− 8%) due to the formation of inorganic precipitates within the core channels.
The primary objective of the experiments is to investigate the relationship between permeability changes and the stages of reinjection, with a focus on the effects of residual oil. The study focuses on identifying the processes occurring up to the point of complete clogging, considering the impact of residual oil saturation in the chalk core samples. Image analysis using scanning electron microscopy, particle size measurement with a zeta-potential meter, and thermodynamic scale formation modeling with ScaleCERE software were employed to explain these processes.
Three stages of permeability change were identified during the injection of 200 pore volumes of produced water: increased permeability (+12%), pressure stabilization, and decreased permeability (− 8%). The positive influence of residual oil saturation on the filtration and storage properties of the reservoir was established, due to the mobilization of chalk core particles. Additionally, the theory of core channel clogging during the reinjection of formation water by the formation of inorganic precipitates within the channels was confirmed.
Understanding the causes of permeability reduction that occurred during the stage of permeability decrease enables the development of water purification methods specifically targeted at the causes of rock clogging. Predicting the process of injecting a mixture of produced and seawater will help in interpreting the data during disposal operations by injecting formation water into an injection well, and it will allow for the selection of effective measures to mitigate the impact on the reservoir.
Crude oil and cadmium (Cd) are common pollutants in Ghana's coastal ecosystems, where the cyanobacterial phytoplankton Synechococcus sp. serves as the primary producer and forms the base of the marine food web alongside small grazers. We hypothesized that cadmium and crude oil would disrupt microbial community structure and function, with the strongest effects under combined exposure. This study investigates the toxic effects of Oil (2 mL L−1), Cd (4.4 μg L−1), and their combined impact (Cd + Oil) on functional groups within the coastal microbial community, including Synechococcus sp., heterotrophic bacteria, nanoflagellates, eukaryotic phytoplankton, ciliates, and dinoflagellates, as well as on copepod nauplii and copepodite development during six-day incubations. We observed acute toxic effects on heterotrophic ciliates and dinoflagellates, with >50 % reductions in abundance within 6 h and a marked decrease in diversity. Phytoplankton showed growth within the first 24 h due to nutrient replenishment from the protist decay, however, their growth continued to decline after 24 h, with Synechococcus being particularly sensitive to Cd and less affected by Oil. In contrast, heterotrophic bacteria increased in abundance across all treatments, likely benefiting from organic matter released during phytoplankton decay and their high adaptability. Notably, the bacterial genera Marivivens and Rhodovulum became dominant mainly in the Oil-amended treatments. Overall, the microbial groups exhibited diverse responses to the pollutants, with the combined Cd + Oil treatment exerting the strongest negative effects, while crude oil alone had the least impact. These findings highlight the vulnerability of tropical microbial food webs, typically dominated by Synechococcus and microbial grazers, to combined pollutant stress, with potential cascading effects on higher trophic levels and coastal ecosystem productivity. This highlights the need for comprehensive monitoring and conservation efforts in these globally significant, yet understudied, regions.
Large volumes of produced water are being discharged globally as byproducts of oil production. Commercial production chemicals are conventionally needed to avoid problems such as bacterial growth, pipe corrosion, and oil/water separation issues. These chemicals will partition between oil and water phases and may affect both treatment processes and the environmental impact when water is discharged to the ocean after treatment. Capillary zone electrophoresis is used to measure partitioning coefficients of oilfield chemicals when these are dissolved in the water phase and in contact with either octanol or crude oil. The technique is fast and, due to simplicity, could have merits as on-site assessment of the partition coefficient for direct assessment of the fate of chemicals. The method was first qualified by estimating partitioning coefficients of aliphatic carboxylic acids and chemicals with a molecular structure similar to those of some production chemicals. Subsequently, the coefficients were determined for two different commercial corrosion inhibitors and a biocide that are used in the oilfield as production chemicals. The results showed that the chemicals predominantly preferred to remain in the water phase after contact with either octanol or crude oil. The partitioning coefficients log(p) spanned between −0.36 and −1.68 in the case of water/octanol contact and between 2.68 and −1.41 in the case of water/crude oil contact. One of the corrosion inhibitors exhibited a significant difference in the partitioning depending on whether the organic phase was octanol or crude oil. The chemical had a preference for the water phase in the case of the former but a preference for the crude oil phase in the case of the latter. The result demonstrates that it makes it challenging to evaluate the use of partitioning coefficients for oilfield applications.
The idea for this project originated within the Arctic Council’s Protection of the Arctic Marine Environment (PAME) Working Group, where a concern was raised about the disposal of tailings from onshore mining operations onto the seafloor. This led to a broader reflection on the impacts of mining operations on the marine environment. Many Arctic governments support the development of a mineral extraction industry, provided it operates in an environmentally responsible manner and considers socio-economic impacts to local communities. However, the environmental impact of existing and future mining operations is often debated. This report summarizes the results of the multi-year Existing Waste Management Practices and Pollution Control for Marine and Coastal Mining project, developed under the auspices of the Protection of the Arctic Marine Environment (PAME) Working Group.
Underwater radiated noise (URN) from ship propellers has attracted increasing interest in recent years due to its adverse environmental effects on marine life and their communication channels. The environmental concern to reduce shipping noise and the industrial requirements for faster computational tools are driving factors that promote research in the specialized domain of hydroacoustics. This thesis deals with the development of such a computationally efficient numerical tool, which can be used in the prediction of underwater radiated noise in the early design phase of propellers.
The numerical model is developed with two major objectives – versatility in assessing the relative contributions from the major propeller-noise generating mechanisms, and rapidity in prediction of overall noise behaviour. It uses the Farassat-1A solid-FWH formulation of the Ffowcs-Williams- Hawkings equation by defining equivalent acoustic sources on the propeller blade, sheet cavity and tip vortex cavity surfaces. In particular, the application of the solid-FWH formulation to the tip vortex cavity model is the major novelty in this thesis.
The hydrodynamic flow solution is obtained from a potential flow based solver ESPPRO, which includes analytical models of sheet cavitation and tip vortex cavitation. The hydroacoustic numerical model developed within this thesis, DoLPHiN, is a Python-based code that is primarily designed to accept input from ESPPRO; but during the research, the code has also been adapted to read input from the commercial, finite-volume-based Navier-Stokes solver, STAR-CCM+.
The numerical model implementations are verified through analytical case studies for simple geometrical shapes, such as a pulsating sphere and an oscillating cylindrical cavity. The verification study is further extended for propeller geometries by identifying approximate reference solutions in simplified operating conditions. The numerical tool is validated for industrial application through comparison of its noise prediction with model-scale and full-scale noise measurements. Specific characteristics of the propeller noise spectrum are identified in order to evaluate its noise prediction capabilities. The uncertainty factors involved when validating with experimental measurements are also explored in detail. Furthermore, a design study is presented, which shows potential use of the numerical tool in practical propeller design and optimization applications.
The European Green Deal (EGD) adopted in December 2019 seeks to facilitate the transition of the EU towards a climate-neutral continent and a modern, resource-efficient, and competitive economy by 2050. In addition to a set of objectives, it is also a policy program that will affect the policy landscape, by driving the development of new directives and regulation, and the amendment of existing ones. In order to facilitate a transition of EU society to better protect the marine environment, decision making and implementation processes within marine governance will need to be improved to develop and implement measures through which EGD marine protection objectives will be achieved.
The Horizon Europe PERMAGOV project aims to improve the implementation and performance of EU marine policies to reach the goals set in the EGD. The PERMAGOV project focuses on four issue areas, so-called regime complexes: Maritime Transport, Marine Energy, Marine Life and Marine Plastics. Within each regime complex, 2 to 3 case studies are used to explore and analyse how governance arrangements are emerging and changing and improving their performance through the EGD. These case studies span three European Seas, the Baltic Sea, the Mediterranean Sea and the North East Atlantic.
Determination of coverage and thickness of marine growth is a useful tool for determining structural loads and drags on marine structures and ships. In this work, we present an algorithmic program based on sonar and optical camera measurements, that estimates both the coverage and thickness of marine-fouling on off-shore structures. The marine-fouling composition is estimated using a Deep-Neural Network, trained using supervised methods, which can distinguish between hard/soft fouling species and the background water and structural components. The marine-fouling thickness is estimated using an HF Forward Looking Sonar, which is applied as a sensitive ultrasonic thickness gauge, when combined with a thickness measurement algorithm. Combined the measurements provide a localized estimate of the marine-fouling coverage and loadings across the structural surfaces, which can be used for automatic inspection evaluation and mission planning.
Plastic litter is introduced into the oceans from land-based sources located in many countries around the world. Marine plastic pollution may therefore be attributable to multiple states, resulting in shared state responsibility. This article discusses the issue of shared state responsibility for land-based marine plastic pollution by examining (i) primary rules of international law concerning the prevention of land-based marine plastic pollution; (ii) secondary rules of international law on this subject; and (iii) possible ways of strengthening the primary rules. It concludes that the barrier for the invocation of state responsibility may become higher in cases of shared state responsibility. Three cumulative solutions to this problem are proposed: elaborating the obligation of due diligence, strengthening compliance procedures, and interlinking regimes governing the marine environment and international watercourses.