The expansion of Carbon Capture, Utilization, and Storage (CCUS) highlights the growing need for carbon dioxide (CO2) pipeline transportation. While pure CO2 is non-corrosive, impurities such as H2O and NO2 create a corrosive environment that risks pipeline integrity. This study investigates how H2O and NO2 concentrations, along with temperature, influence corrosion under CO2 pipeline conditions. The investigation was performed in an autoclave setup emulating a linear velocity of 0.96 m/s at 100 bar and temperatures of 5 °C and 25 °C, testing X52 and GR70, and a more corrosion-resistant 9Cr alloy. The results indicated that the presence of NO2 elevated the corrosion rate compared to scenarios without. Low H2O concentration led to a corrosion rate of up to five times higher at 5 °C, compared to at 25 °C, in the presence of NO2. Low to moderate corrosion was observed for the carbon steels without NO2 and with 70 ppmv H2O at both temperatures. Reducing the H2O concentration below 70 ppmv and removing NO2, while SO2 and O2 are present, will only result in low to moderate corrosion in the carbon steel CO2 pipeline. The corrosion rate for X52 and GR70 was 0.065 mm/y and 0.016 mm/y higher or 5 and 3 times greater, respectively, at 5 °C compared to 25 °C. The study concludes that H2O should be maintained below 70 ppmv and NO2 should be eliminated to prevent severe corrosion. Emphasizing the importance of CO2 specification compliance and the need for further research into CO2 compositions that align with the specifications.