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Towards improved antifouling: Exploring xanthan gum hydrogel coatings

Marcel Butschle, Shawn Lindner, Markus Schackmann, Kim Dam-Johansen

This study explored xanthan gum hydrogel coatings as an approach to more environmental friendly fouling control strategies. Xanthan gum served as a filler in a conventional rosin/acrylic coating matrix, leading to the formation of a 150 μm thick gel layer on the coating surface upon seawater exposure. While biocide-free xanthan hydrogel coatings did not have significant antifouling capabilities, a synergistic effect between hydrogel and cuprous oxide was observed. During field tests at the CoaST Maritime Test Center (CMTC), it was found that the cuprous oxide concentration could be reduced by at least 50 wt% for the hydrogel coating without compromising the antifouling performance. Two possible causes were identified. First, the hydrogel coating could maintain a higher release rate over a prolonged period and second, the hydrogel was able to accumulate Cu2+, increasing retention time on the surface, creating a hostile environment. A synergistic enhancement in gel strength, yield point, and flow point was observed when xanthan was combined with konjac mannan. While promising for static applications, the rheological assessments of the different gels highlighted challenges for the application in dynamic settings like moving ships.

Progress in Organic Coatings / 2024
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Port selection by container ships: A big AIS data analytics approach

Hongxiang Feng, Qin Lin, Xinyu Zhang, Jasmine Lam*, Wei Yim Yap

Port selection is of vital importance for both port operators and shipping lines. In this contribution, an Automatic Identification System (AIS) big data approach is developed. This approach allows identifying container ships using only AIS data without the need for supplementary information from commercial databases. This approach is applied to investigate the port selection statistics of container ships between Shanghai and Ningbo Zhoushan Port, two of the largest ports in the world in terms of calling frequency, to generate practical insights. Results show that: i) the ratios among large ships, medium ships and small ships of these two ports are both approximately 1: 4: 5; ii) these two ports both have an exclusive (i.e., more feeder ports covered in geographical coverage) and intensive (i.e., more feeder ships deployed in shipping service frequency) collection and distribution network mainly consisting of small ships, but that of Shanghai is more intensive; iii) in terms of ultra-large ships over 380 m, Shanghai has accommodated an extra 18.5% compared to that of Ningbo Zhoushan, this indicates Shanghai's attraction for such vessels in global fleet deployment; iv) the feeder network between Shanghai and Ningbo Zhoushan is weak, and their relationship is actually in competition; v) Ningbo Zhoushan could offer more choices for ultra-large container ships (over 380 m), which implies its greater potential in future port competition; vi) when the depth of channels and berths is sufficient, the distance to hinterland and the convenience of a collection and distribution network begin to get more important in port selection. The empirical findings unveil the decision-making of container lines, competition between ports and implications for shipping policy.

Research in Transportation Business and Management / 2024
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Mapping the biofouling activities of aged fouling release coating surfaces undergoing underwater cleaning

Shujie Lin, Huichao Bi, Claus Erik Weinell, Kim Dam-Johansen

The effectiveness of fouling release coatings (FRCs) may diminish over time in the seawater. Underwater cleaning of FRCs in service is crucial for biofouling control. This study investigated the effects of cleaning parameters (brush moving speed, cleaning force and frequency) on a silicone-based FRC (SiFR) aged for 2 months (A2-SiFR) and 13 months (A13-SiFR), simulating the short-term and long-term FRCs in service. Fouling resistance, re-fouling and cleaning efficiency utilizing a self-designed automated underwater cleaning system (AUCS) were examined. Moreover, coating surface characterization, including visual appearance condition, roughness, water contact angle were evaluated on the testing surfaces. Field testing at the CoaST Maritime Test Centre (CMTC) demonstrated that underwater cleaning exhibited positive effect on the long-term fouling control performance of aged FRCs. Besides, stronger cleaning force, slower moving speed and biweekly cleaning led to better fouling resistance. No significant damages were observed on A2-SiFR surface, while regular spiral and circular scratches appeared on A13-SiFR surface. The damages led to adverse effects on fouling resistance, re-fouling and cleaning efficiency of algae on the cleaned A13-SiFR surface, affecting the coating performance more than cleaning parameters. Despite these damages, the cleaned surfaces still exhibited a higher fouling resistance compared with the ones without cleaning.

Applied Ocean Research / 2024
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Integration of unmodified kraft lignin powder in waterborne coatings and investigation of antifouling properties

Marcel Butschle*, Richard Schlautek, Lisa Kunschert, Markus Schackmann, Claus Erik Weinell, Kim Dam-Johansen

Antifouling properties of unmodified kraft lignin for potential use in marine coatings were investigated. The study was based on preliminary findings that pointed toward lignin’s efficacy against seawater organisms during laboratory tests. Coatings were formulated that contained lignin as a filler and had a pigment volume concentration above the critical pigment volume concentration. This ensured direct interaction between lignin and seawater organisms, as the lignin particles remained incompletely wetted by the binder. Moreover, all formulations were waterborne to mitigate the release of volatile organic compounds. Despite the initial promise, the antifouling performance of the formulated lignin coatings during field experiments at the CoaST Maritime Test Center was limited, and the anticipated mechanism must be reconsidered. Additionally, it was found that high lignin concentrations, while facilitating organism interaction, compromised the coating's mechanical properties. Nevertheless, the waterborne coating formulation introduced here might provide a foundation for other researchers to further investigate lignin’s potential as a bio-based pigment or a filler in coatings.

Journal of Coatings Technology and Research / 2024
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High-order Spatial Interactions Enhanced Lightweight Model for Optical Remote Sensing Image-based Small Ship Detection

Yifan Yin, Xu Cheng*, Fan Shi*, Xiufeng Liu, Huan Huo, Shengyong Chen

Accurate and reliable optical remote sensing image-based small-ship detection is crucial for maritime surveillance systems, but existing methods often struggle with balancing detection performance and computational complexity. In this paper, we propose a novel lightweight framework called HSI-ShipDetectionNet that is based on high-order spatial interactions and is suitable for deployment on resource-limited platforms, such as satellites and unmanned aerial vehicles. HSI-ShipDetectionNet includes a prediction branch specifically for tiny ships and a lightweight hybrid attention block for reduced complexity. Additionally, the use of a high-order spatial interactions module improves advanced feature understanding and modeling ability. Our model is evaluated using the public Kaggle and FAIR1M marine ship detection datasets and compared with multiple state-of-the-art models including small object detection models, lightweight detection models, and ship detection models. The results show that HSI-ShipDetectionNet outperforms the other models in terms of detection performance while being lightweight and suitable for deployment on resource-limited platforms.

IEEE Transactions on Geoscience and Remote Sensing / 2024
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GreenHopper: The Danish spearhead towards autonomous waterborne mobility

Mogens Blanke, Nicholas Hansen, Kjeld Dittmann, Thomas Thuesen Enevoldsen, Dimitrios Dagdilelis, Frederik Emil Thorsson Saabye Schöller, Martin Krarup Plenge-Feidenhans'l, Jonathan Binner Becktor, Dimitrios Papageorgiou, Roberto Galeazzi

GreenHopper is the first Danish zero-emission ferry developed as a test platform for autonomous waterborne navigation technologies. The paper presents technology development within the innovation project ShippingLab Autonomy, which led to the commissioning of GreenHopper at Limfjorden (DK) in December 2022. The technology research resulted in a holistic system architecture for surface vessel autonomy, based on distribution of functionality and responsibility on software modules, similar to the structure observed in the International Maritime Organization (IMO) Seafarers Training Certification and Watch-keeping (STCW) regulatory framework. The paper shows how this approach results in an architecture that supports safe behaviours of individual modules and of autonomous navigation at a system level. The paper presents the individual modules, specific features and benefits. Elements of the regulatory framework are highlighted to poise technology approval by maritime authorities. The paper reflects on lessons learned, discusses continued technology validation in dedicated operational scenarios.

Journal of Physics: Conference Series / 2024
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Evaluating the impact of Northern Sea Route fuel costs on bilateral trade between China and the EU

Ran Zhang, Jasmine Siu Lee Lam, Zhuo Sun*

The accelerated melting of the Arctic ice leads to the navigation of the Northern Sea Route (NSR) linking Asia and Europe, shortening transport channel between China and the European Union (EU). This has a significant impact on the China-EU bilateral trade which is analyzed in the present study. We present a framework based on a general equilibrium model for analyzing the impact of the NSR on the trade and the economies of China and the EU. Different fuel cost scenarios, consisting of fuel prices and sailing speeds on ice, are also considered. Specifically, we measure the changes in shipping costs between China and the EU, brought about by NSR navigation. These are used as a basis to quantify changes in transport technology. The Global Trade Analysis Project (GTAP) model is used to predict the trade and economic impacts. The results show that the NSR can save 0.98% in shipping costs and generate an increase in the exports of China and the EU in the order of 14,986 and 8,228 million US dollars, respectively. Among these exports, the mining industry shows the fastest growth, while the electronics industry experiences the largest increase in trade volume. Our findings reveal the potential of the NSR as an alternative route and its positive impact on bilateral trade between China and the EU. The results can provide a basis for shipping companies and governments to make decisions regarding the use of Arctic routes.

Maritime Economics and Logistics / 2024
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Energy extraction potential from wave-induced ship motions using linear generators

Ulrik D. Nielsen*, Harry B. Bingham, Rasmus Bjørk

This paper presents an assessment of the energy harvesting potential from wave-induced motions when producing electricity by linear generators installed on ships. The study estimates an upper maximum energy extraction potential by not considering the electro-mechanical coupling; neither is mechanical and electrical dissipation considered. The analysis of the harvested energy is made using simulated data in a case study investigating three different ships (by size). Specifically, the case study reveals that, in moderate to mildly severe sea states, the power harvested from the environment using linear generators may reach values around 1–2 kW/tons of seismic mass. Thus, it is unrealistic to imagine ship designs where linear generators are thought to provide a ship's necessary propulsion power but, on the other hand, they may serve to supplement the main engine for auxiliary power generation.

Sustainable Energy Technologies and Assessments / 2024
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Developing correction factors for weather’s influence on the energy efficiency indicators of container ships using model-based machine learning

Amandine Godet, Lukas Jonathan Michael Wallner, George Panagakos, Michael Bruhn Barfod*

The International Maritime Organization employs technical and operational indicators to assess ship energy efficiency. Weather conditions significantly impact ship fuel consumption during voyages, necessitating the consideration of this influence in energy efficiency calculations. This study aims to design models for estimating the impact of weather components on fuel consumption and develop correction factors to cope with the weather effect on the fuel consumption of container ships for different sea states. Using model-based machine learning, the study analyzes noon reports and hindcasted weather data from two sister container ships. It quantifies weather-induced fuel consumption across various sea states, ranging from 2% to 20%, with an average of 7%–13% depending on the model used. Correction factors specific to each sea state are derived, and different approaches for their integration into energy efficiency indicators are proposed. This study advocates tailored weather correction factors for energy efficiency metrics tied to specific sea states, emphasizing the need for standardized weather impact assessments. Prior to any formal policy application, future work is needed to address the limitations of the present study and extend this approach to various ship types and sizes and different geographical regions.

Ocean and Coastal Management / 2024
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Bi-Layered Real-Time Energy Management Strategy for Hybrid Power Systems in Hydrogen Fuel Cell Vessels

Yuji Zeng, Qinjin Zhang, Shi You, Yancheng Liu, Herbert H. C. Iu, Haohao Guo, Siyuan Liu

Existing energy management strategies (EMSs) for hybrid power systems (HPSs) in hydrogen fuel cell vessels (FCVs) are not applicable to scenarios with multiple hydrogen fuel cells (FCs) and lithium batteries (LBs) in parallel, and are difficult to achieve real-time control and optimization for multiple objectives. In this paper, a bi-layer real-time energy management strategy (BLRT-EMS) is proposed. Compared with existing EMSs, the proposed BLRT-EMS implements different control/optimization objectives distributed in the execution layer EMS (EL-EMS) and the decision layer EMS (DL-EMS), which can significantly reduce bus voltage fluctuations, decrease hydrogen consumptions, improve the system efficiency, and have potential for engineering applications. In the first EL-EMS, a decentralized optimal power allocation strategy is proposed, which allows each FC system to allocate the output power ratio according to their generation costs, ensuring consistent performance of multiple FC systems (MFCS) under long-term operating conditions, and thus delaying the degradation rate of FCs. In the second EL-EMS, a distributed cooperative control strategy is proposed to achieve dynamic SoC equalization, proportional output power allocation, and accurate bus voltage restoration among multiple battery storage systems (MBSS) to extend the service life of batteries. In the DL-EMS, an energy coordination optimization strategy between MFCS and MBSS is proposed to achieve hydrogen consumption reduction and system efficiency improvement, thus enhancing the endurance performance of FCV. Finally, test results based on the StarSim experimental platform show that the proposed BLRT-EMS has faster SoC convergence speed, smaller bus voltage deviation, lower hydrogen consumption, higher system efficiency, and lower operation stress than the state-of-the-art methods.

IEEE Transactions on Transportation Electrification / 2024
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